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Beilstein J. Org. Chem. 2005, 1, No. 5, doi:10.1186/1860-5397-1-5
Graphical Abstract
Figure 1: Alkylidenation approach to the synthesis of allenylsilanes.
Scheme 1: Synthesis of substituted silylketenes 1
Scheme 2: Reaction of substituted silylketenes with ester-stabilised phosphoranes
Scheme 3: Reaction of silylketenes with various ylides
Scheme 4: Methylenation of silylketene 1b with the Lombardo reagent
Scheme 5: Methylenation of silylketenes with the Petasis reagent